The code might look something like this:
objXL = ObjectCreate("Excel.Application")
objConstants = ObjectConstantsGet(objXL)
objXL.Visible = @TRUE
objXL.WorkBooks.Open("C:\temp\data\test.xls")
objXL.Columns("A:A").Select
objSelection = objXL.Selection
objSelection.NumberFormat = "Number"
objSelection.HorizontalAlignment = objConstants.xlLeft
objSelection = 0
objConstants = 0
objXL = 0
Message("Notice","Column A - format successfully changed")
Exit
Reference:
http://techsupt.winbatch.com/webcgi/webbatch.exe?techsupt/tsleft.web+WinBatch/OLE~COM~ADO~CDO~ADSI~LDAP/OLE~with~Excel+Format~Excel~Column.txt
http://techsupt.winbatch.com/webcgi/webbatch.exe?techsupt/tsleft.web+WinBatch/OLE~COM~ADO~CDO~ADSI~LDAP/OLE~with~Excel+Excel~-~constants.txt
http://msdn.microsoft.com/en-us/library/office/ff196401(v=office.15).aspx
http://msdn.microsoft.com/en-us/library/office/ff822120(v=office.15).aspx